Issue 1, 1973

Mechanism of the redox isomerisation of af-dichloro-bc-bis(pyridine)-de-trimethyleneplatinum(IV) to the platinum(II) complex of pyridinium propylide [PtCl2(C5H5NCHEt)(py)]

Abstract

Kinetic and other results on the reaction of af-dichloro-bc-bis(pyridine)-de-trimethyleneplatinum(IV) in benzene forming the platinum(II) ylide trans-[PtCl2(C5H5NCHEt)(py)] are presented; a dissociative mechanism is suggested.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 102-105

Mechanism of the redox isomerisation of af-dichloro-bc-bis(pyridine)-de-trimethyleneplatinum(IV) to the platinum(II) complex of pyridinium propylide [PtCl2(C5H5NCHEt)(py)]

R. D. Gillard and M. F. Pilbrow, J. Chem. Soc., Dalton Trans., 1973, 102 DOI: 10.1039/DT9730000102

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