Formation of metal carbonyl derivatives of monothiocarbamates, dithiocarbamates, ureas, and thioureas from organotin intermediates

Abstract

The easily accessible trimethyltin dithiocarbamato-, monothiocarbamato-, ureido-, and thioureido-compounds have been shown to be useful reagents for the preparation of metal carbonyl complexes of these ligands. New dimeric manganese carbonyl-monothiocarbamato-, -ureido- and -thioureido-compounds are recorded and structures are proposed based upon the spectra of these new types of complex.