(B6H10)2PtCl2 is a trans-square-planar complex with the platinum bridge-bonded to the unique (4,5-position) basal boron atoms in each of the B6H10 ligands; the bridged B–B bond is nearly perpendicular to the Cl–Pt–Cl axis.
J. P. Bernnan, R. Schaeffer, A. Davison and S. S. Wreford, J. Chem. Soc., Chem. Commun., 1973, 354a DOI: 10.1039/C3973000354A
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