Crystal structure analysis of {(C6H6)Ru[B(pz)4]}+PF6– where B(pz)4 represents the tetrakis-(1-pyrazolyl)borate group, has shown that the B(pz)4 ligand is tridentate and the benzene ring is hexahapto.
R. J. Restivo and G. Ferguson, J. Chem. Soc., Chem. Commun., 1973, 847 DOI: 10.1039/C39730000847
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