The complex [(PMe2Ph)4CIReN2MoCI4(OMe)] has been prepared; it has µ(N2) at 1660 cm–1 and the N–N (1·21 Å), Re–N (1·79 Å), and Mo-N (1·89 Å) bond distances, determined by X-ray crystallography are consistent with a linear Re–N–N–Mo delocalised bonding scheme.
M. Mercer, R. H. Crabtree and R. L. Richards, J. Chem. Soc., Chem. Commun., 1973, 808 DOI: 10.1039/C39730000808
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