Hydrogen exchange between organic compounds and heavy water is homogeneously catalysed by sodium chloroiridite; results for alkylbenzenes are compared with those from heterogeneous catalysis by iridium metal and are interpreted in terms of the role of π-complex intermediates.
J. L. Garnett, M. A. Long, A. B. McLaren and K. B. Peterson, J. Chem. Soc., Chem. Commun., 1973, 749 DOI: 10.1039/C39730000749
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