Issue 18, 1973

The sigmatropic rearrangements of 2-oxyanilinium ylides

Abstract

The [1,4] sigmatropic rearrangement of the anilinium ylides derived from the salts (1) is an intramolecular process, (1)→(2); the N-allyl ylide (8) reacts, in addition, by a sequence of [2,3] and [3,3] sigmatropic rearrangements to give the allyl phenol (10).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 653-654

The sigmatropic rearrangements of 2-oxyanilinium ylides

W. D. Ollis, I. O. Sutherland and Y. Thebtaranonth, J. Chem. Soc., Chem. Commun., 1973, 653 DOI: 10.1039/C39730000653

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