The dominant factor in determining the thermodynamic stability of the metal–olefin bond in p-substituted styrene complexes of palladium(II) has been shown to be the olefin-π to metal-d component of the bond, rather than the metal-d to olefin-π* component.
E. M. Ban, R. P. Hughes and J. Powell, J. Chem. Soc., Chem. Commun., 1973, 591 DOI: 10.1039/C39730000591
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