Issue 15, 1973

Electronic considerations in metalloboranes

Abstract

A 2n+ 14 electron rule is proposed for closo n-vertex polyhedral heteraoboranes containing one transition-metal vertex; nido-polyhedra of this type ruquire 2n+ 16 electrons while closo-polyhedra with two transition metal vertical require 2n+ 26 electrons.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 543-544

Electronic considerations in metalloboranes

C. J. Jones, W. J. Evans and M. F. Hawthorne, J. Chem. Soc., Chem. Commun., 1973, 543 DOI: 10.1039/C39730000543

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