The reaction of hot recoil tritium atoms with neopentane can generate excited neopentane molecules which decompose by breaking the C–C bond nearest the labelling site; the excess energy is therefore not equilibrated before decomposition, τ½(neopentane–3H)*ca. 120 ps.
G. K. Winter and D. S. Urch, J. Chem. Soc., Chem. Commun., 1973, 474 DOI: 10.1039/C39730000474
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