The Δ22cis- and trans-C26 sterols (1) and (2) from a Wittig synthesis have been separated; the properties of the cis-isomer (1) may be explained by the obstruction to the free rotation of the side chain.
A. Metayer and M. Barbier, J. Chem. Soc., Chem. Commun., 1973, 424 DOI: 10.1039/C39730000424
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