Acetolysis of D-homo-5α-androstan-17aβ-yl tosylate (I) gave the 17aβ-yl acetate (II) accompanied by D-homo-5α,13α-androstan-17aα-yl acetate (III), resulting from inversion of configuration at the quaternary centre adjacent to the reaction site.
I. Khattak, D. N. Kirk, C. M. Peach and M. A. Wilson, J. Chem. Soc., Chem. Commun., 1973, 341 DOI: 10.1039/C39730000341
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