Hydrogen bonding between tet b and perchlorate ions stabilizes [Cu(tet b)]2Cl3+ which contains trigonal bipyramidal co-ordinate Cu2+ with an almost linear Cu–Cl–Cu bridge and with the tet b ligand in its most stable, folded form.
R. A. Bauer, W. R. Robinson and D. W. Margerum, J. Chem. Soc., Chem. Commun., 1973, 289 DOI: 10.1039/C39730000289
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