The crystal structure of Cu4[SC(NH2)2]10-(SiF6)2,H2O has been determined and found to consist of six-membered rings of alternating Cu and S atoms connected by sulphur bridges to form chains, which are in turn interconnected via a Cu2S2 four-membered ring to form a three-dimensional polymer.
A. G. Gash, E. H. Griffith, W. A. Spofford and E. L. Amma, J. Chem. Soc., Chem. Commun., 1973, 256 DOI: 10.1039/C39730000256
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