Gallium oxide catalyses with high selectivity the exchange with deuterium of vinylic and allylic hydrogens in a variety of alkenes, and directly interconverts cis and trans isomers of butenes and pentenes at temperatures well below those required for double-bond shift.
F. B. Carleton, H. A. Quinn and J. J. Rooney, J. Chem. Soc., Chem. Commun., 1973, 231 DOI: 10.1039/C39730000231
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