Crystal structure analysis of tetrafluoroethylene-1,1,1-tris(diphenylphosphinomethyl)ethanenickel has established that the phosphine ligand is tridentate through three phosphorus atom; the co-ordinated C2F4 group is highly distorted, each CF2 being bent away from the planar conformation by an average of 42°.
J. Browning and B. R. Penfold, J. Chem. Soc., Chem. Commun., 1973, 198 DOI: 10.1039/C39730000198
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