Issue 18, 1972
From the journal:

Journal of the Chemical Society, Dalton Transactions

Temperature dependence of conductivity of some partly-oxidised platinum complexes

T. W. Thomas,   Che-hsiung Hsu,   M. M. Labes,   P. S. Gomm,   A. E. Underhill  and  D. M. Watkins  

Abstract

The conductivity of single crystals of K2Pt(CN)4Cl0·32·6H2O, K1·6Pt(C2O4)xH2O, Mg0·82Pt(C2O4)5·3H2O and K1·74Pt(CN)41·8H2O has been determined. The temperature dependence of the conductivity follows a log σ∝–(1/T)½ relationship consistent with a phonon-assisted hopping model recently proposed. In the last complex a metal-like temperature dependence of conductivity is observed at T > 243 K, which resembles the metal–insulator transition observed in a one-dimensional organic solid.

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Article information

DOI
https://doi.org/10.1039/DT9720002050
Article type
Paper

J. Chem. Soc., Dalton Trans., 1972, 2050-2053

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Temperature dependence of conductivity of some partly-oxidised platinum complexes

T. W. Thomas, C. Hsu, M. M. Labes, P. S. Gomm, A. E. Underhill and D. M. Watkins, J. Chem. Soc., Dalton Trans., 1972, 2050 DOI: 10.1039/DT9720002050

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