Issue 16, 1972
From the journal:

Journal of the Chemical Society, Dalton Transactions

Transition metal complexes as ligands: preparation of mixed transition metal complexes of niobium with nickel, palladium, platinum, or molybdenum

W. E. Douglas  and  M. L. H. Green  

Abstract

The dithio-derivatives (π-C5H5)2Nb(SR)2, R = Me or Ph and [(π-C5H5)2Nb(SMe)2]+A– have been prepared. The bismethylthio-derivative forms the diamagnetic, trinuclear complexes {[(π-C5H5)2Nb(SMe)2]2M}2+A22–, where M = Ni, Pd, or Pt. The bonding in the trinuclear complexes is discussed. A paramagnetic compound (π-C5H5)2Nb(SMe)2Mo(CO)4 and a bridging-oxo-derivative [(π-C5H5)2NbCl]2O]+BF4– are also described.

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Article information

DOI
https://doi.org/10.1039/DT9720001796
Article type
Paper

J. Chem. Soc., Dalton Trans., 1972, 1796-1800

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Transition metal complexes as ligands: preparation of mixed transition metal complexes of niobium with nickel, palladium, platinum, or molybdenum

W. E. Douglas and M. L. H. Green, J. Chem. Soc., Dalton Trans., 1972, 1796 DOI: 10.1039/DT9720001796

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