The enthalpies and activation energies of dissociation of the ligand, L, from the complexes PtXCH3A2L (where X = Cl or Br; A = AsMe3 or AsMe2Ph; and L = tetrafluoroethylene or hexafluorobut-2-yne are reported. A value for the bond energy, E(Pt–C4F6) is calculated.
C. T. Mortimer, J. L. McNaughton and R. J. Puddephatt, J. Chem. Soc., Dalton Trans., 1972, 1265 DOI: 10.1039/DT9720001265
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