SCHEDULED MAINTENANCE:
The sila-adamantyl silicon-centred radical is readily formed from trimethyltetrasila-adamantane in the reaction with CCl4 initated by dibenzoyl peroxide and was found to have a selectivity toward halogen abstraction similar to that of simple triorganosilyl radicals when the reaction was carried out with CBrCl3.
G. D. Homer and L. H. Sommer, J. Chem. Soc., Chem. Commun., 1972, 1249a DOI: 10.1039/C3972001249A
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