Ziegler-type systems, M(acac)n–AlEt3(M = Ni, Co, Fe) catalyse the hydrosilylation of 1,3-dienes; with RC⋮CH, hydrosilylation is accompanied by linear dimerisation to give CH2:CR·CR:CHSiX3 as the major product.
M. F. Lappert and S. Takahashi, J. Chem. Soc., Chem. Commun., 1972, 1272 DOI: 10.1039/C39720001272
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