Photoreduction of tetrakis-(1,10-phenanthroline)-diaquo-µ-oxo-di-iron(III) in aqueous medium to form [Fe(phen)3]2+(phen = 1,10-phenanthroline) seems to continue even after cessation of irradiation; kinetic evidence supports the formulation of a thermally labile peroxo-bridged binuclear complex, which undergoes thermal reduction and rearrangement to [FeII(phen)3]2+.
P. G. David, J. Chem. Soc., Chem. Commun., 1972, 1151 DOI: 10.1039/C39720001151
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