Issue 19, 1972

Unexpectedly low reactivity for spirosilanes: 4-sila-spiro[3,3]heptane

Abstract

Competitive cleavages of 4-silaspiro[3,3]heptane (I), 4-silaspiro[3,5]nonane (III), and 1,1-dimethylsilacyclobutane (III) by hydrogen chloride in diethyl ether have been carried out; the unexpectedly low reactivity of (I) is discussed in terms of a model controlled by steric considerations.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 1068-1069

Unexpectedly low reactivity for spirosilanes: 4-sila-spiro[3,3]heptane

R. Damrauer, R. A. Karn and M. T. Burke, J. Chem. Soc., Chem. Commun., 1972, 1068 DOI: 10.1039/C39720001068

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements