Photolysis of 4-diazocyclohexa-2,5-dienones gives rise to CIDNP spectra indicating that cyclohexadienone carbene reacts in a singlet state, whereas its di-t-butyl derivative reacts as a triplet.
M. L. Kaplan and H. D. Roth, J. Chem. Soc., Chem. Commun., 1972, 970 DOI: 10.1039/C39720000970
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