Nucleophilic displacement of cobalt from alkylcobalt(IV) complexes takes place with inversion of configuration at the α-carbon and probably accounts for the inversion of configuration found in alkyl halides obtained from the reaction between the corresponding alkylcobalt(III) complexes and halogens.
S. N. Anderson, D. H. Ballard, J. Z. Chrzastowski, D. Dodd and M. D. Johnson, J. Chem. Soc., Chem. Commun., 1972, 685 DOI: 10.1039/C39720000685
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