Issue 10, 1972
From the journal:

Journal of the Chemical Society, Chemical Communications

The trans-influence of the ligand trimethylsilylmethylide (Me3SiCH2–) in platinum(II) complexes and the crystal structure of a platinum(II) alkyl

M. R. Collier,   C. Eaborn,   Borjana Jovanović,   M. F. Lappert,   Ljubica Manojlović-Muir,   K. W. Muir  and  Margaret M. Truelock  

Abstract

Spectroscopic and crystallographic data are presented for trans-[PtCl(CH2SiMe3)(PMe2Ph)2]; by comparison of data for cis-[Pt(CH2Y)2(PMe2Ph)2] and trans-[PtCl(CH2Y)(PMe2Ph)2](Y = H, Ph, or Me3Si) it is concluded that the trans-influence of the ligands decreases in the order Ph2MeSi– > YCH2–, and that the group Y has a minor role.

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Article information

DOI
https://doi.org/10.1039/C39720000613
Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 613-614

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The trans-influence of the ligand trimethylsilylmethylide (Me3SiCH2–) in platinum(II) complexes and the crystal structure of a platinum(II) alkyl

M. R. Collier, C. Eaborn, B. Jovanović, M. F. Lappert, L. Manojlović-Muir, K. W. Muir and M. M. Truelock, J. Chem. Soc., Chem. Commun., 1972, 613 DOI: 10.1039/C39720000613

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