A five-co-ordinate rhodium(0) dimer: the crystal and molecular structure of tetrakis(triphenylphosphine)di-µ-carbonyl-dirhodium(0)–bisdichloromethane solvate
Abstract
[(PPh3)2Rh(CO)]2,2CH2Cl2 is a five-co-ordinate dimer linked by two carbonyl bridges and a metal–metal bond, with a Rh–Rh separation of 2·630(2)Å.