An intermolecular ‘ene’ reaction of an aliphatic nitroso-compound with an olefin leading to a stable nitroxide radical with a β-hydrogen is described, together with the first example of an analogous intramolecular process.
W. B. Motherwell and J. S. Roberts, J. Chem. Soc., Chem. Commun., 1972, 329 DOI: 10.1039/C39720000329
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