The first example of a compound containing a tertiary carbon atom bonded to a transition metal has been prepared by platination of PBu2t(o-PriPh): some metallations of the secondary carbon atom of an ortho-ethylphenyl group, are also described.
D. F. Gill and B. L. Shaw, J. Chem. Soc., Chem. Commun., 1972, 65 DOI: 10.1039/C39720000065
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