Volume 67, 1971

Mechanism of ligand substitution in weak complexes. Part 4

Abstract

For Al[Co(CN)6] the thermodynamics and kinetics of the reaction outer-sphere complex ⇌ inner-sphere complex have been investigated. From measurements with the pressure-jump relaxation technique between 10 and 40°C the rates and energies of activation have been obtained. The equilibrium constants were determined by the conductometric method and from the amplitude of the relaxation effect.

Article information

Article type
Paper

Trans. Faraday Soc., 1971,67, 2101-2107

Mechanism of ligand substitution in weak complexes. Part 4

C. Kuehn and W. Knoche, Trans. Faraday Soc., 1971, 67, 2101 DOI: 10.1039/TF9716702101

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