The bromination of 3,5-dimethoxytoluene (1), 3-hydroxy-5-methoxytoluene (22), methyl 2-hydroxy-4-methoxy-6-methylbenzoate (27), methyl 3,5-dimethoxybenzoate (36), and 3,5-dihydroxybenzoic acid (42) has been investigated. Hydrogen bromide-catalysed rearrangements encountered in these studies are described.
J. R. Cannon, T. M. Cresp, B. W. Metcalf, M. V. Sargent, G. Vinciguerra and J. A. Elix, J. Chem. Soc. C, 1971, 3495 DOI: 10.1039/J39710003495
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