The mechanism of the peroxy-acid-catalysed cyclisation of N-(o-acylaminophenyl)pyrrolidine (and related systems), which has been suggested to occur by way of an N-oxide intermediate, has been established by formation of such an N-oxide [N-(2-benzoylaminophenyl)pyrrolidine N-oxide] and its cyclisation under acidic conditions.
O. Meth-Cohn, J. Chem. Soc. C, 1971, 1356 DOI: 10.1039/J39710001356
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