7β-Cyano-6,14-endo-etheno-7α-methyl-6,7,8,14-tetrahydrothebaine (1) on treatment with phenylmagnesium bromide gives the expected imine (2) and a C-4 phenolic by-product (4). Fission of the bicyclo-octene system accompanies acid hydrolysis of the imine.
J. W. Lewis and M. J. Readhead, J. Chem. Soc. C, 1971, 1161 DOI: 10.1039/J39710001161
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