SCHEDULED MAINTENANCE:
Bromination of 2,5-disubstituted 6a-thiathiophthens [1,6,6aS(IV)-trithiapentalenes] yields monosubstitution products, but nitrosation is accompanied by rearrangement, leading to 3-nitrosomethylene-1,2-dithioles in which the oxygen atom of the nitroso-group is probably bonded to the adjacent sulphur atom. 2-Methylthio-5-phenyl-6a-thiathiophthen undergoes nitration in the 3-position.
R. J. S. Beer, D. Cartwright, R. J. Gait and D. Harris, J. Chem. Soc. C, 1971, 963 DOI: 10.1039/J39710000963
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