Issue 0, 1971

Crystal structure of ferrocenylmethyl(dimethyl)ammonium tetrachlorozincate monohydrate

Abstract

Crystals of ferrocenylmethyl(dimethyl)ammonium tetrachlorozincate monohydrate, [C5H5FeC5H4·CH2·NHMe2+]2 ZnCl42–, H2O are monoclinic, a= 18·076(6), b= 14·038(5), c= 12·246(5)Å, β= 95·70(1)°, Z= 4, space group P21/c. The structure was determined with Mo-Kα scintillation counter data by direct methods, and was refined by least-squares procedures, the final R being 0·068 for 2012 observed reflexions. The mean bond distances are Fe–C 2·04 and C–C (cyclopentadienyl rings) 1·43 Å. Groups of four cations, two anions, and two water molecules (two formula units) are linked around centres of symmetry by N–H ⋯ Cl (3·11 Å), N–H ⋯ O (2·76 Å), and O–H ⋯ Cl (3·05, 3·17 Å) hydrogen bonds.

Article information

Article type
Paper

J. Chem. Soc. A, 1971, 2659-2662

Crystal structure of ferrocenylmethyl(dimethyl)ammonium tetrachlorozincate monohydrate

C. S. Gibbons and J. Trotter, J. Chem. Soc. A, 1971, 2659 DOI: 10.1039/J19710002659

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