Issue 0, 1971

Magnetic anisotropy and polarized electronic spectrum of dichlorotetrakis(thiourea)nickel(II)

Abstract

The magnetic anistropies and powder susceptibilities of Ni(thiourea)4Cl2 are reported in the temperature range 80–300 K, together with single-crystal polarized electronic spectra at room- and liquid-helium-temperatures. The results are interpreted within a C4v crystal-field model including spin–orbit coupling.

Estimates of the crystal-field radial parameters Dq, Dt, and Ds are made by fitting the magnetic and spectral results, as are values for the spin–orbit coupling and orbital reduction factors.

Article information

Article type
Paper

J. Chem. Soc. A, 1971, 2434-2440

Magnetic anisotropy and polarized electronic spectrum of dichlorotetrakis(thiourea)nickel(II)

M. Gerloch, J. Lewis and W. R. Smail, J. Chem. Soc. A, 1971, 2434 DOI: 10.1039/J19710002434

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