Titanium tetrachloride forms a 1 : 1 addition compound with o-allylaniline which involves five-co-ordinate titanium(IV); the o-allyl group is not co-ordinated to the metal atom. Aniline forms 1 : 1 (five-co-ordinate) and 1 : 2 (six-co-ordinate) addition compounds with titanium tetrachloride and 1 : 2 addition compounds (six-co-ordinate) with titanium tetrabromide.
D. A. Baldwin and R. J. H. Clark, J. Chem. Soc. A, 1971, 1725 DOI: 10.1039/J19710001725
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