The 35Cl nuclear quadrupole frequencies of 23 boron-chlorine compounds are presented and discussed in terms of the s-character and charge distribution in the B–Cl band. An approximate order of donor ability for a ligand L in compounds of the type BCl3,L is proposed on the basis of the 35Cl frequencies.
J. A. S. Smith and D. A. Tong, J. Chem. Soc. A, 1971, 178 DOI: 10.1039/J19710000178
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