Tetrakispentafluorophenylcyclotetra-arsine reacts with Fe(CO)5 giving Fe(CO)4(AsC6F5)2, in which the molecule (AsC6F5)2 contains an As–As linkage and is bonded by each As atom to Fe; (PC6F5)4, however, yields Fe3(CO)9(PC6F5)2 and traces of [Fe(CO)3]2(PC6F5)4 under similar conditions.
P. S. Elmes, P. Leverett and B. O. West, J. Chem. Soc. D, 1971, 747b DOI: 10.1039/C2971000747B
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