During the reaction of tungsten(V) chloride with trichloroacetonitrile addition across the cyanide bond occurred to give di-µ-chloro-bis[tetrachloro(pentachloroethylnitrido)tungsten(VI)] which contains a tungsten–nitrogen multiple bond of length 1·71(2)Å.
M. G. B. Drew, G. W. A. Fowles, D. A. Rice and N. Rolfe, J. Chem. Soc. D, 1971, 231b DOI: 10.1039/C2971000231B
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