The four-co-ordinate iridium(I) compound, Ir(O2S-p-tolyl)(CO)(PPh3)2 has O-bonded sulphinate but uptake of carbon monoxide or dioxygen results in isomerisation to S-bonded sulphinate while addition of methyl iodide leaves the ligand O-bonded.
C. A. Reed and W. R. Roper, J. Chem. Soc. D, 1971, 1556 DOI: 10.1039/C29710001556
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