Dehydrobromination of either 1,2-dibromo-1-methylcyclohexane or 1,2-dibromo-4-methylcyclohexane, in a bis-(2-methoxyethyl) ether–sodium methoxide mixture, produces products unusually rich in the exocyclic isomer 3-methylenecyclohexene.
C. W. Spangler, L. W. Hardy and R. J. Bayer, J. Chem. Soc. D, 1971, 1416 DOI: 10.1039/C29710001416
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