In the complex [(mda)3NaCl], (mda =p,p′-diaminodiphenylmethane) each amino-group is hydrogen-bonded to one Cl– and co-ordinated to one Na+; the co-ordination round Na+ is nearly octahedral (Na–N 2·52 Å) and that round Cl– nearly trigonal prismatic (Cl–N 3·44 Å).
J. A. J. Jarvis and P. G. Owston, J. Chem. Soc. D, 1971, 1403 DOI: 10.1039/C29710001403
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