A series of optically active linear tetradentate ligands, which form six-, as well as five-membered chelate rings, has been stereospecifically synthesized and used to prepare the complexes trans-Co(N4)Cl2+ in an attempt to correlate the signs of the Cotton effects with the known chiralities of the new compounds.
L. J. DeHayes, M. Parris and D. H. Busch, J. Chem. Soc. D, 1971, 1398 DOI: 10.1039/C29710001398
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