Irradiation of o-bromostyrene in the presence of Fe(CO)5 leads to the formation of ferraindenetricarbonyliron [C8H6Fe2(CO)6] and ferraindenebistricarbonyliron [C8H6Fe3(CO)9]via dehydrobromination, in addition to complexes derived from direct co-ordination of the original substrate.
R. Victor, R. Ben-Shoshan and S. Sarel, J. Chem. Soc. D, 1971, 1241 DOI: 10.1039/C29710001241
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