Reaction of [Ru(PPh3)3HCl] with [ArN2]]BF4](Ar =p-MeC6H4 or p-MeOC6H4) gave [Ru(N2Ar)2(PPh3)2Cl][BF4]; reduction with sodium amalgam in ethanol affords ArNH2 and NH3, oxidation with chlorine gives [Ru(N2Ar)(PPh3)2Cl3], and with [Ru(PPh3)3Cl2], [ArN2][BF4] affords [Ru(N2Ar)(PPh3)2Cl2]2[BF4]2.
J. A. McCleverty and R. N. Whiteley, J. Chem. Soc. D, 1971, 1159 DOI: 10.1039/C29710001159
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