An analysis of the secondary solvent isotope effect and of the solvent effect in methanol–water mixtures on the rate of bromination of pent-1-ene indicates that the transition state for this reaction is highly polarized and essentially solvated through hydrogen bonding.
F. Garnier, R. H. Donnay and J. E. Dubois, J. Chem. Soc. D, 1971, 829 DOI: 10.1039/C29710000829
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