Four-co-ordinate iridium(I) cations containing various combinations of the ligands, CO, MeCN, Me2SO, PPh3, PPh2Me, and PPh2Et are described including an X-ray structural analysis of [Ir(PPh2Me)4]BF4: the ability of these cations to co-ordinate oxygen is found to be sensitive to steric factors.
G. R. Clark, C. A. Reed, W. R. Roper, B. W. Skelton and T. N. Waters, J. Chem. Soc. D, 1971, 758 DOI: 10.1039/C29710000758
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