The kinetics of the autocatalysed bromination of anisole (ArH) in CCl4 has been found to be first order in ArH, Br2, and HBr, but with IBr as catalyst, the orders are 1, 1, and 2, respectively; a common mechanism is believed to operate.
D. C. Rao, J. Rajaram and J. C. Kuriacose, J. Chem. Soc. D, 1971, 754 DOI: 10.1039/C29710000754
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