Issue 13, 1971

X-Ray determination of molecular structures of molybdenum(IV) oxo-complexes. The possibility of a new type of isomerism

Abstract

Notable differences between corresponding bond lengths and interbond angles in the complexes blue cis-mer-[MoOCl2(PMe2(Ph)3] and green cis-mer-[MoOCl2(PEt2Ph)3] are caused by ligand repulsions; an explanation of the isomerism of mer-[MoOCl2(PMe2Ph)3] is suggested in terms of the structures of the above complexes.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 655-656

X-Ray determination of molecular structures of molybdenum(IV) oxo-complexes. The possibility of a new type of isomerism

J. Chatt, L. Manojlović-Muir and K. W. Muir, J. Chem. Soc. D, 1971, 655 DOI: 10.1039/C29710000655

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